Safety Tips Workplace exposure

Prevent hydrogen sulfide exposure

Hydrogen sulfide is a highly flammable hazardous gas that occurs naturally in crude petroleum and natural gas. It also is present in sewage, created through the breakdown of organic matter, and can cause negative health effects when inhaled. Hydrogen sulfide is heavier than air so it tends to be more highly concentrated in low-lying areas that are poorly ventilated, such as basements, manholes, sewer lines, and underground telephone or electrical vaults.

Health effects

Hydrogen sulfide’s effect on individuals varies depending on the levels of exposure. For most individuals (asthmatics may be at greater risk for ill health effects from exposure):

  • Low concentrations cause irritation of the eyes, nose, throat and respiratory system. This reaction can be delayed.
  • Moderate concentrations cause more severe eye and respiratory effects, headache, dizziness, nausea, vomiting, coughing and difficulty breathing.
  • High concentrations can lead to shock, convulsions and inability to breathe. In some instances, high levels of exposure can lead to coma and death. This effect can take place very rapidly, after only a few breaths.

Detecting the presence

Although low levels of concentration hydrogen sulfide may be detected by a “rotten egg” smell, high levels of concentration or being exposed to low levels for an extended period of time can cause a worker to lose the ability to smell the gas. Sense of smell alone is not a reliable method to indicate the presence of hydrogen sulfide.

Avoiding exposure

Before entering areas where hydrogen sulfide may be present, have a qualified person test the air. This will indicate whether fire or explosion precautions are necessary.

If the gas is present, the area should be ventilated. If the gas cannot be removed, workers should be equipped with proper personal protective, rescue and communication equipment. A self-contained breathing apparatus is required in spaces with a concentration higher than 100 parts per million.

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Devit John
April 25, 2014
Our organization ASK-EHS Engineering and Consultant provides a Hydrogen Sulfide safety online training module that is use on every oil and petrochemical, Mining Industry and waste water treatment plant and numerous areas that have been aware of H2S hazards. As stated by the Agency for Toxic Substances & Disease Registry, individuals who work in specific commercial enterprises could be laid open to larger amounts of hydrogen sulfide than the all inclusive community. These businesses incorporate mining, mash and paper plants, petroleum and characteristic gas boring operations, and sewage medicine plants. Individuals must be particularly cautious when working in spaces, for example, storm cellars, sewer vents, sewers and compost pits on the grounds that hydrogen sulfide is heavier than air, permitting it to traverse the ground and fill low-lying spaces.

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Cath Swan
April 13, 2018
I work in the wastewater sector in the UK. The article suggests that breathing apparatus is only required in spaces with H2S concentration higher than 100ppm. In the UK our short term workplace exposure limit (working for just 15 minutes) is 10parts per million and just 5ppm for long term exposure, as published in the Health and Safety Executive's EH40 tables. I appreciate accepted levels may differ by country but I think the 100ppm value is a typo and it's worth checking local regulations. Worth noting that between 50-100ppm H2S can cause permanent eye damage, it is very nasty stuff so please take care!